1,2-Polybutadiene Latices by Catalytic Polymerization in Aqueous Emulsion
نویسندگان
چکیده
منابع مشابه
1,2-Polybutadiene Latices by Catalytic Polymerization in Aqueous Emulsion
Catalytic aqueous polymerization of butadiene by the cobalt catalyst system [Co(C8H13)(C4H6)]/CS2 affords colloidally stable latices of highly crystalline syndiotactic 1,2-polybutadiene (Tm ) 190 °C, ∆Hc ) 60 J/g, Mw ∼ 105 g/mol, 97% 1,2, 3% 1,4-cis). Catalyst modification with reagents containing electrophilic carbon atoms (e.g., aromatic formamides) strongly decreases polymer crystallinity (T...
متن کاملSubmicron polyethylene particles from catalytic emulsion polymerization.
Particles of linear polyethylene (M(n) = (2-3) x 10(3) g x mol(-)(1); M(w)/M(n) = 2-4) obtained by catalytic emulsion polymerization of ethylene possess a nonspherical, lentil-like shape with an average aspect ratio of ca. 10 and diameters from 30 to >300 nm, as determined by TEM and AFM. The particle structure results from a stacking of the lamellae along the one shorter axis of the lentils (i...
متن کاملSingle Lamella Crystals of Polyethylene Accessible by Catalytic Emulsion-Polymerization
INTRODUCTION Since many decades, polyethylene (PE) is one of the commodity polymers which has become ubiquitous because of its low price and good mechanical properties. Hence, the number of applications of the material is huge and many millions of tons are produced worldwide annually. However, PE has hardly played any role in the emerging field of nanotechnology so far. This is due to the probl...
متن کاملCatalytic Polymerization of Ethylene in Aqueous Emulsion with a Simple in Situ Catalyst
Catalytic polymerization of ethylene in aqueous emulsion by in situ catalysts based entirely on compounds commercially available from standard chemicals suppliers, namely a chlorinated derivative of 1,4-benzoquinone, triphenylphosphine, and bis(1,5-cyclooctadiene)nickel, is reported. Using miniemulsions of catalyst solutions in a small amount of hydrocarbon solvent for polymerization, stable di...
متن کاملAqueous Catalytic Polymerization of Olefins
Aqueous catalytic polymerization may seem like a contradiction at first sight. The high water sensitivity of Ziegler or Phillips catalysts applied commercially for the production of polyolefins is well known. However, water offers a unique combination of properties as a medium for polymerization reactions: A high heat capacity, which enables an effective transfer of the heat of polymerization. ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Macromolecules
سال: 2005
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma050621i